Inorganic Solid Phases

[Co(H2O)6]K2[As6CoMo6O30] (KMo3CoAs3O15[H2O]3) Crystal Structure

General Information

  • Phase Label(s): KMo3CoAs3O15[H2O]3
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cP208
  • Space Group: 205
  • Phase Prototype: KMo3CoAs3O15[H2O]3
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4F (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of cell and structural parameters), T = 298 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement, R = 0.032; wR = 0.032
  • Sample Detail(s): sample prepared from Na3As3Mo3O15[H2O]10, Co[H2O]6Cl2, KCl, chemical analysis; 22.36 wt.% As, 31.29 wt.% Mo, 6.08 wt.% Co, 4.25 wt.% K, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: KMo3CoAs3O15[H2O]3
  • Alphabetic Formula: As3Co[H2O]3KMo3O15
  • Published Formula: [Co(H2O)6]K2[As6CoMo6O30]
  • Refined Formula: As3CoH6KMo3O18
  • Wyckoff Sequence: 205,d8cba
  • Z Formula Units: 8
  • Density: ρ = 3.64 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1001432

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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