Inorganic Solid Phases

Cd3[Co(CN)6]2·12H2O (CdCo0.67[CN]4[H2O]4.33) Crystal Structure

General Information

  • Phase Label(s): CdCo0.67[CN]4[H2O]4.33
  • Structure Class(es): Nasicon family, Prussian blue
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cF56
  • Space Group: 225
  • Phase Prototype: CdCo0.67[CN]4
  • Measurement Detail(s): automatic diffractometer; 15 (determination of cell parameters), automatic diffractometer; Syntex P1 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): cyanide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, least-squares refinement; 150 reflections; I > 3σ(I), R = 0.043; wR = 0.055
  • Sample Detail(s): sample prepared from CdCl2, H3Co[CN]6, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: CdCo0.67[CN]4[H2O]4
  • Alphabetic Formula: [CN]4CdCo0.67[H2O]4
  • Published Formula: Cd3[Co(CN)6]2·12H2O
  • Refined Formula: C4CdCo0.67H7.99N4O4
  • Wyckoff Sequence: 225,fe3cba
  • Z Formula Units: 4
  • Density: ρ = 1.83 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1001441

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied