Inorganic Solid Phases

[Co(NH3)6][HgCl3]3·H2O (Hg3CoCl9[NH3]6[H2O], T = 133 K) Crystal Structure

General Information

  • Phase Label(s): Hg3CoCl9[NH3]6[H2O]
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP80
  • Space Group: 14
  • Phase Prototype: Hg3CoCl9[NH3]6[H2O]
  • Measurement Detail(s): automatic diffractometer; 25 (determination of cell parameters), automatic diffractometer; Nicolet R3m (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of cell and structural parameters), T = 133 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): chloride, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, block-diagonal least-squares refinement; 146 variables; 2480 reflections; I > 3σ(I), R = 0.0450; wR = 0.0456
  • Sample Detail(s): sample prepared from Co[NH3]6Cl3, HgCl2, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Hg3CoCl9[NH3]6[H2O]
  • Alphabetic Formula: Cl9Co[H2O]Hg3[NH3]6
  • Published Formula: [Co(NH3)6][HgCl3]3·H2O
  • Refined Formula: Cl9CoH20Hg3N6O
  • Wyckoff Sequence: 14,e20
  • Z Formula Units: 4
  • Density: ρ = 3.52 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1003833

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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