Inorganic Solid Phases

Rb3Ti3P5O20:V4+ (Rb3Ti3[PO4]3[P2O7]O rt, T = 300 K) Crystal Structure

General Information

  • Phase Label(s): Rb3Ti3[PO4]3[P2O7]O rt
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: oP124
  • Space Group: 29
  • Phase Prototype: K3Ti3[PO4]3[P2O7]O
  • Measurement Detail(s): automatic diffractometer; 24 (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4F (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters), T = 300 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): orthophosphate, diphosphate, oxide
  • Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement; 2276 reflections; I > 2σ(I), R = 0.038
  • Sample Detail(s): sample prepared from Rb2O, P2O5, V2O5, TiO2 rutile, chemical analysis; 0.06-0.12 wt.% V4+ detected, single crystal (determination of cell parameters), single crystal, 0.12×0.36×0.40 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Rb3Ti3[PO4]3[P2O7]O
  • Alphabetic Formula: O[PO4]3[P2O7]Rb3Ti3
  • Published Formula: Rb3Ti3P5O20:V4+
  • Refined Formula: O20P5Rb3Ti3
  • Wyckoff Sequence: 29,a31
  • Z Formula Units: 4
  • Density: ρ = 3.41 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1012929

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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