Inorganic Solid Phases

β-trans-[Pd(NH3)2Cl2] (PdCl2[NH3]2 orth) Crystal Structure

General Information

  • Phase Label(s): PdCl2[NH3]2 orth
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: oP24
  • Space Group: 55
  • Phase Prototype: PdCl2[NH3]2
  • Measurement Detail(s): automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): chloride
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 38 variables; 445 reflections; I > 2σ(I), R = 0.0569
  • Sample Detail(s): sample prepared from α-trans-(Pd[NH3]2Cl2), NH4Cl, NH4NO3 or KCl, chemical analysis; 13.2 wt.% N, 2.8 wt.% H, 33.5 wt.% Cl, 50.3 wt.% Pd, single crystal, 0.2 mm side length (determination of structural parameters)

Substance Summary

  • Standard Formula: PdCl2[NH3]2
  • Alphabetic Formula: Cl2[NH3]2Pd
  • Published Formula: β-trans-[Pd(NH3)2Cl2]
  • Refined Formula: Cl2H6N2Pd
  • Wyckoff Sequence: 55,hg2feda
  • Z Formula Units: 4
  • Density: ρ = 2.72 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1020877

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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