Inorganic Solid Phases

ZnxCo3−xO4, x= 0.99(1) (ZnCo2O4) Crystal Structure

General Information

  • Phase Label(s): ZnCo2O4
  • Structure Class(es): spinel family
  • Classification by Properties: ferromagnet FM, hard magnet, semiconductor
  • Mineral Name(s):
  • Pearson Symbol: cF56
  • Space Group: 227
  • Phase Prototype: MgAl2O4
  • Measurement Detail(s): automatic diffractometer; Russia, Dubna, Joint Institute for Nuclear Research, Frank Laboratory of Neutron Physics, IBR-2 reactor, DN-2 (determination of structural parameters), neutrons, time-of-flight (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide
  • Interpretation Detail(s): complete structure determined; composition dependence studied, Rietveld refinement, RP = 0.023; wRP = 0.023
  • Sample Detail(s): sample prepared from ZnyCo2−y[OH]3NO3, atomic emission spectroscopy, complexometry, X-ray fluorescence spectroscopy; Zn0.99(1)Co2.01O4, powder (determination of structural parameters)

Substance Summary

  • Standard Formula: Zn0.99Co2.01O4
  • Alphabetic Formula: Co2.01O4Zn0.99
  • Published Formula: ZnxCo3−xO4, x= 0.99(1)
  • Refined Formula: Co2.01O4Zn0.99
  • Wyckoff Sequence: 227,ecb
  • Z Formula Units: 8
  • Density: ρ = 6.17 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1021175

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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