Inorganic Solid Phases

[{Na2(H2O)4(OH)2}{Na(H2O)4}2{(Zn(H2O)3)2(W(H2O)2)2(SbW9O33)2}]·8H2O (Na2ZnW10SbO33[OH][H2O]15) Crystal Structure

General Information

  • Phase Label(s): Na2ZnW10SbO33[OH][H2O]15
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP252
  • Space Group: 14
  • Phase Prototype: Na2ZnW10SbO33[OH][H2O]15
  • Measurement Detail(s): automatic diffractometer; 6791 (determination of cell parameters), automatic diffractometer; Bruker AXS SMART APEX II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 293 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, oxide, hydrate
  • Interpretation Detail(s): positions of non-H and part of H atoms determined, full-matrix least-squares refinement on F2; 568 variables; 8923 reflections; I > 2σ(I), R = 0.0485; wR = 0.1199
  • Sample Detail(s): sample prepared from SbCl3, Na2WO4[H2O]2, ZnSO4[H2O]7, chemical analysis; 1.09 wt.% H, 2.31 wt.% Zn, 4.30 wt.% Sb, 64.61 wt.% W, 1.56 wt.% Na, single crystal (determination of cell parameters), single crystal, 0.20×0.20×0.26 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Na2ZnW10SbO33[OH][H2O]15
  • Alphabetic Formula: [H2O]15Na2O33[OH]SbW10Zn
  • Published Formula: [{Na2(H2O)4(OH)2}{Na(H2O)4}2{(Zn(H2O)3)2(W(H2O)2)2(SbW9O33)2}]·8H2O
  • Refined Formula: H28Na2O49SbW10Zn
  • Wyckoff Sequence: 14,e63
  • Z Formula Units: 4
  • Density: ρ = 3.63 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1022446

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied