Inorganic Solid Phases

Sn5.22Ti0.80Li1.73(Fe5.74Zn6.13Mn0.10)(Al44.84Mg0.78)O90(OH)6 (Li0.6Mg0.3Zn2.0Ti0.4Fe1.9Al15.0Sn1.6O30[OH]2) Crystal Structure

General Information

  • Phase Label(s): Li0.6Mg0.3Zn2.0Ti0.4Fe1.9Al15.0Sn1.6O30[OH]2
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s): ferronigerite/zinconigerite-6N6S
  • Pearson Symbol: hR162
  • Space Group: 166
  • Phase Prototype: Zn1.4Fe3Al14.8Sn2.2O30[OH]2
  • Measurement Detail(s): automatic diffractometer; 25 (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, oxide
  • Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement; 76 variables; 1868 reflections; I > 2σ(I), R = 0.0201; wR = 0.0531
  • Sample Detail(s): nigerite sample from Nigeria, Kabba Province, Egbe District, electron microprobe analysis; 54.13 wt.% Al2O3, 18.63 wt.% SnO2, 11.81 wt.% ZnO, 9.76 wt.% FeO, 1.51 wt.% TiO2, 0.74 wt.% MgO, 0.61 wt.% Li2O, 0.17 wt.% MnO, 0.05 wt.% SiO2, 0.02 wt.% Co, 0.01 wt.% Cr2O3, 0.01 wt.% NiO, single crystal (determination of cell parameters), single crystal, 0.05×0.20×0.30 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Li0.58Mg0.26Zn2.06Ti0.27Fe2.08Al14.95Sn1.74O30[OH]2
  • Alphabetic Formula: Al14.95Fe2.08Li0.58Mg0.26O30[OH]2Sn1.74Ti0.27Zn2.06
  • Published Formula: Sn5.22Ti0.80Li1.73(Fe5.74Zn6.13Mn0.10)(Al44.84Mg0.78)O90(OH)6
  • Refined Formula: Al14.78Fe1.99H2Li0.57Mg0.26O32Sn1.74Ti0.26Zn2.12
  • Wyckoff Sequence: 166,h5edc9
  • Z Formula Units: 3
  • Density: ρ = 4.44 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1121172

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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