Inorganic Solid Phases

[Ru(NO)(NH3)3(H2O)Cl][Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O (Ru4Cl11[NO]4[OH][NH3]8[H2O]3) Crystal Structure

General Information

  • Phase Label(s): Ru4Cl11[NO]4[OH][NH3]8[H2O]3
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mS140
  • Space Group: 9
  • Phase Prototype: Ru4Cl11[NO]4[OH][NH3]8[H2O]3
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 293(2) K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, chloride, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement on F2; 227 variables, R = 0.0362; wR = 0.0757
  • Sample Detail(s): sample prepared from [NH4]2(Ru[NO]Cl5), NH4CH3COO, HCl, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Ru4Cl11[NO]4[OH][NH3]8[H2O]3
  • Alphabetic Formula: Cl11[H2O]3[NH3]8[NO]4[OH]Ru4
  • Published Formula: [Ru(NO)(NH3)3(H2O)Cl][Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O
  • Refined Formula: Cl11H31N12O8Ru4
  • Wyckoff Sequence: 9,a35
  • Z Formula Units: 4
  • Density: ρ = 2.33 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1126309

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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