Inorganic Solid Phases

NH4N3·2As2O3 ([NH4]As4[N3]O6) Crystal Structure

General Information

  • Phase Label(s): [NH4]As4[N3]O6
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hP14
  • Space Group: 191
  • Phase Prototype: [NH4]As4[N3]O6
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Oxford Diffraction Gemini A Ultra (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters), T = 293(2) K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): azide, oxide
  • Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement on F2; 171 reflections, R = 0.0192; wR = 0.0388
  • Sample Detail(s): sample prepared from NH4AsO2, NaN3, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: [NH4]As4[N3]O6
  • Alphabetic Formula: As4[NH4][N3]O6
  • Published Formula: NH4N3·2As2O3
  • Refined Formula: As4H4N4O6
  • Wyckoff Sequence: 191,iheba
  • Z Formula Units: 1
  • Density: ρ = 3.29 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1141983

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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