Inorganic Solid Phases

[(NH3)3Co(OH)(NO2)2Co(NH3)3]Cl3·H2O (Co2[NO2]2Cl3[OH][NH3]6[H2O]) Crystal Structure

General Information

  • Phase Label(s): Co2[NO2]2Cl3[OH][NH3]6[H2O]
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP76
  • Space Group: 14
  • Phase Prototype: Co2[NO2]2Cl3[OH][NH3]6[H2O]
  • Measurement Detail(s): Weissenberg photographs (determination of cell and structural parameters), X-rays, Fe Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): nitrite, hydroxide, chloride, hydrate
  • Interpretation Detail(s): positions of non-H and part of H atoms determined, full-matrix least-squares refinement; 173 variables; 1397 reflections, R = 0.067
  • Sample Detail(s): single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Co2[NO2]2Cl3[OH][NH3]6[H2O]
  • Alphabetic Formula: Cl3Co2[H2O][NH3]6[NO2]2[OH]
  • Published Formula: [(NH3)3Co(OH)(NO2)2Co(NH3)3]Cl3·H2O
  • Refined Formula: Cl3Co2H21N8O6
  • Wyckoff Sequence: 14,e19
  • Z Formula Units: 4
  • Density: ρ = 1.93 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Anisotropic

Site
B11 [nm2]
B22 [nm2]
B33 [nm2]
B12 [nm2]
B13 [nm2]
B23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1211822

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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