Inorganic Solid Phases

Zn(H2O)3.5[(UO2)2(SO4)O2] (Zn2[UO2]4[SO4]2[OH]8[H2O]3) Crystal Structure

General Information

  • Phase Label(s): Zn2[UO2]4[SO4]2[OH]8[H2O]3
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mS140
  • Space Group: 12
  • Phase Prototype: Zn2[UO2]4[SO4]2[OH]8[H2O]3
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS P3 SMART APEX (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, sulfate, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, least-squares refinement on F2; 97 variables; 1222 reflections; F > 4σ(F), R = 0.0457; wR = 0.0771
  • Sample Detail(s): sample prepared from UO3, ZnSO4[H2O]7, HCl, twinned crystal (determination of cell parameters), twinned crystal, 0.010×0.015×0.080 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Zn2[UO2]4[SO4]2O4[H2O]7
  • Alphabetic Formula: [H2O]7O4[SO4]2[UO2]4Zn2
  • Published Formula: Zn(H2O)3.5[(UO2)2(SO4)O2]
  • Refined Formula: H14O27S2U4Zn2
  • Wyckoff Sequence: 12,j12i9hg
  • Z Formula Units: 4
  • Density: ρ = 5.03 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1217304

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied