Inorganic Solid Phases

Pb1−xBi4+xTi4−xMnxO15, x= 0.6 (Ti3.5Mn0.5Pb0.5Bi4.5O15) Crystal Structure

General Information

  • Phase Label(s): Ti3.5Mn0.5Pb0.5Bi4.5O15
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: oS96
  • Space Group: 36
  • Phase Prototype: (Ti0.75Fe0.25)4Bi5O15
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Indonesia, Serpong, Material Science Research Center, RSG-GAS reactor, DN3 (determination of structural parameters), neutrons; λ = 0.18195 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide
  • Interpretation Detail(s): complete structure determined; composition dependence studied, Rietveld refinement, RP = 0.1129; wRP = 0.1487; RB = 0.0646
  • Sample Detail(s): sample prepared from TiO2 rutile, Mn2O3, Bi2O3, PbO, powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Ti3.4Mn0.6Pb0.4Bi4.6O15
  • Alphabetic Formula: Bi4.6Mn0.6O15Pb0.4Ti3.4
  • Published Formula: Pb1−xBi4+xTi4−xMnxO15, x= 0.6
  • Refined Formula: Bi4.60Mn0.60O15Pb0.40Ti3.40
  • Wyckoff Sequence: 36,b11a2
  • Z Formula Units: 4
  • Density: ρ = 8.09 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1225762

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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