Inorganic Solid Phases

cuprammine exchanged NaX zeolite (H15NaCu3Al22Si26O96[NH3]12[H2O]10) Crystal Structure

General Information

  • Phase Label(s): H15NaCu3Al22Si26O96[NH3]12[H2O]10
  • Structure Class(es): zeolite FAU
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cF784
  • Space Group: 227
  • Phase Prototype: H15NaCu3(Al0.46Si0.54)48O96[NH3]12[H2O]10
  • Measurement Detail(s): automatic diffractometer (determination of cell and structural parameters), X-rays, Cu Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): silicate, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, Rietveld refinement; 75 reflections; F > 3σ(F), RB = 0.09
  • Sample Detail(s): sample prepared from Na-X zeolite, Cu[NO3]2[H2O]3, NH4[OH], flame spectroscopy, gravimetry; 23.58 wt.% H2O, 21.950 wt.% Si, 17.390 wt.% Al, 8.120 wt.% Cu, 4.328 wt.% Na, powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: H15NaCu3Al22Si26O96[NH3]12[H2O]10
  • Alphabetic Formula: Al22Cu3H15[H2O]10[NH3]12NaO96Si26
  • Published Formula: cuprammine exchanged NaX zeolite
  • Refined Formula: Al22.08Cu2.68H55.20N12Na0.92O105.60Si25.92
  • Wyckoff Sequence: 227,ihg4fe2
  • Z Formula Units: 4
  • Density: ρ = 1.49 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1408807

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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