Inorganic Solid Phases

K10Na12[{Co3(B-β-SiW9O33(OH))(B-β-SiW8O29(OH)2)}2]·49H2O (K10Na12W34Co6[SiO4]4O108[OH]6[H2O]49, T = 173 K) Crystal Structure

General Information

  • Phase Label(s): K10Na12W34Co6[SiO4]4O108[OH]6[H2O]49
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP1000
  • Space Group: 14
  • Phase Prototype: K10Na12W34Co6[SiO4]4O108[OH]6[H2O]49
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS D8 SMART APEX (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 173 K (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, orthosilicate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, least-squares refinement; 17543 reflections; I > 2σ(I), R = 0.060; wR = 0.0145
  • Sample Detail(s): sample prepared from CoCl2[H2O]6, K8[γ-SiW10O36], chemical analysis; K/Na/W/Co/Si ratio 3.7/3.0/61.2/3.3/1.3, single crystal (determination of cell parameters), single crystal, 0.06×0.10×0.14 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: K10Na12W34Co6[SiO4]4O108[OH]6[H2O]49
  • Alphabetic Formula: Co6[H2O]49K10Na12O108[OH]6[SiO4]4W34
  • Published Formula: K10Na12[{Co3(B-β-SiW9O33(OH))(B-β-SiW8O29(OH)2)}2]·49H2O
  • Refined Formula: Co6H98K10Na2O179Si4W34
  • Wyckoff Sequence: 14,e250
  • Z Formula Units: 4
  • Density: ρ = 4.19 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1420104

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied