Inorganic Solid Phases

Na4[NH4]6[Bi2W20Zn2O70(H2O)6][H2O]38 (Na2[NH4]3ZnW10BiO35[H2O]22, T = 213(2) K) Crystal Structure

General Information

  • Phase Label(s): Na2[NH4]3ZnW10BiO35[H2O]22
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: aP149
  • Space Group: 2
  • Phase Prototype: Na2[NH4]3ZnW10BiO35[H2O]22
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; STOE IPDS (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters), T = 213(2) K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement on F2; 5666 reflections, R = 0.0878
  • Sample Detail(s): sample prepared from Na12Bi2W22O74[OH]2][H2O]44, ZnSO4[H2O]7, NH4Cl, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Na2[NH4]3ZnW10BiO35[H2O]22
  • Alphabetic Formula: Bi[H2O]22[NH4]3Na2O35W10Zn
  • Published Formula: Na4[NH4]6[Bi2W20Zn2O70(H2O)6][H2O]38
  • Refined Formula: BiH50Na2O60W10Zn
  • Wyckoff Sequence: 2,i74g
  • Z Formula Units: 2
  • Density: ρ = 4.04 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1510501

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied