Inorganic Solid Phases

Bi1/3Pb1/6Zr2(PO4)8/3(SiO4)1/3 (Zr4Pb0.33Bi0.67[SiO4]0.67[PO4]5.33) Crystal Structure

General Information

  • Phase Label(s): Zr4Pb0.33Bi0.67[SiO4]0.67[PO4]5.33
  • Structure Class(es): Nasicon family
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hR105
  • Space Group: 148
  • Phase Prototype: CaTi4[PO4]6
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), X-rays, Cu Kα (determination of cell parameters)
  • Phase Class(es):
  • Compound Class(es): orthophosphate, orthosilicate
  • Interpretation Detail(s): cell parameters determined and structure type assigned
  • Sample Detail(s): sample prepared from Bi[NO3]3[H2O]5, Pb[NO3]2, ZrOCl2[H2O]8, Si(OC2H5)4, ammonium phosphate, chemical analysis; Bi/Zr ratio 0.163, Pb/Zr ratio 0.079, Zr/P ratio 0.710, Bi/P ratio 0.116, Pb/P ratio 0.056, Si/P ratio 0.091, powder (determination of cell parameters)

Substance Summary

  • Standard Formula: Zr4Pb0.33Bi0.67[SiO4]0.67[PO4]5.33
  • Alphabetic Formula: Bi0.67[PO4]5.33Pb0.33[SiO4]0.67Zr4
  • Published Formula: Bi1/3Pb1/6Zr2(PO4)8/3(SiO4)1/3
  • Refined Formula:
  • Wyckoff Sequence:
  • Z Formula Units: 3
  • Density: ρ = 3.70 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1520390

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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