Inorganic Solid Phases

Rb0.92Mn[Fe(CN)6]0.95·1.03H2O LT (RbMnFe[CN]6[H2O] rt) Crystal Structure

General Information

  • Phase Label(s): RbMnFe[CN]6[H2O] rt
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: tI24
  • Space Group: 119
  • Phase Prototype: Rb0.42Mn0.54Fe0.5[CN]3[H2O]0.22
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Philips PW1830 (determination of structural parameters), X-rays, Cu Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): cyanide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, Rietveld refinement, multiphase, wRP = 0.2348
  • Sample Detail(s): sample prepared from MnCl2[H2O]4, K3Fe[CN]6, RbCl, chemical analysis; C20.00Fe15.20H0.25Mn15.51N22.61O4.19Rb22.24; Rb0.92Mn(Fe[CN]6)0.95[H2O]1.03; amounts of high-temperature phase (87.7 wt.%, main phase), powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Rb0.92MnFe0.95[CN]5.7[H2O]1.03
  • Alphabetic Formula: [CN]5.7Fe0.95[H2O]1.03MnRb0.92
  • Published Formula: Rb0.92Mn[Fe(CN)6]0.95·1.03H2O LT
  • Refined Formula: C5.70Fe0.95H2.76MnN5.70O1.38Rb0.92
  • Wyckoff Sequence: 119,g2e2dcba
  • Z Formula Units: 2
  • Density: ρ = 2.09 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1522538

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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