Inorganic Solid Phases

Cu25(V0.57Sn0.43)3(Sb0.08As0.92)4S32 (Cu12.9VSn0.9Sb0.3As1.8S16) Crystal Structure

General Information

  • Phase Label(s): Cu12.9VSn0.9Sb0.3As1.8S16
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s): colusite
  • Pearson Symbol: cP66
  • Space Group: 218
  • Phase Prototype: Cu13V(Sn0.33As0.67)3S16
  • Measurement Detail(s): Weissenberg photographs; 6 (determination of cell parameters), precession and Weissenberg photographs (determination of structural parameters), X-rays, Cu Kα1; λ = 0.154051 nm (determination of cell parameters), X-rays (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): sulfide
  • Interpretation Detail(s): complete structure determined, trial-and-error
  • Sample Detail(s): colusite sample from, sample prepared from colusite, electron microprobe analysis; Cu25.04(V0.57Sn0.43)3.25(Sb0.08As0.92)4.00S31.68; small amounts of Fe detected, single crystal (determination of cell parameters), single crystal, 0.02 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Cu25V1.71Sn1.29Sb0.32As3.68S32
  • Alphabetic Formula: As3.68Cu25S32Sb0.32Sn1.29V1.71
  • Published Formula: Cu25(V0.57Sn0.43)3(Sb0.08As0.92)4S32
  • Refined Formula: As3.68Cu25S32Sb0.32Sn1.29V1.71
  • Wyckoff Sequence: 215,i4e2dcba
  • Z Formula Units: 1
  • Density: ρ = 4.38 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1600246

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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