Inorganic Solid Phases

Na2K5.4[SbW6O24](NO3)0.4·12H2O (K5.4Na2W6Sb[NO3]0.4O24[H2O]12) Crystal Structure

General Information

  • Phase Label(s): K5.4Na2W6Sb[NO3]0.4O24[H2O]12
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hR174
  • Space Group: 166
  • Phase Prototype: K5.4Na2W6Sb[NO3]0.4O24[H2O]12
  • Measurement Detail(s): automatic diffractometer; 11864 (determination of cell parameters), automatic diffractometer; Rigaku R-AXIS RAPID (determination of structural parameters), X-rays, Mo Kα; λ = 0.071075 nm (determination of cell and structural parameters), T = 298 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): nitrate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement on F2; 57 variables; 731 reflections; I > 2σ(I), R = 0.0191; wR = 0.0502
  • Sample Detail(s): sample prepared from WO3, K[OH], KSb[OH]6, Na[NO3], energy-dispersive X-ray analysis, inductive coupled plasma method; 1.14 wt.% H, 0.26 wt.% N, 2.12 wt.% Na, 9.99 wt.% K, 5.88 wt.% Sb, 51.4 wt.% W, single crystal (determination of cell parameters), single crystal, 0.04×0.11×0.13 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: K5.4Na2W6Sb[NO3]0.4O24[H2O]12
  • Alphabetic Formula: [H2O]12K5.4[NO3]0.4Na2O24SbW6
  • Published Formula: Na2K5.4[SbW6O24](NO3)0.4·12H2O
  • Refined Formula: H24K5.40N0.40Na2O37.20SbW6
  • Wyckoff Sequence: 166,ih5gfcba
  • Z Formula Units: 3
  • Density: ρ = 3.72 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1603811

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied