Inorganic Solid Phases

[Rh(NH3)5Cl]-exchanged zeolite NaX, Si/Al= 1.2, 26 % exchange (Na16.1Rh2.85Al21.8Si26.2Cl2.85O96[NH3]14.25[H2O]55.8) Crystal Structure

General Information

  • Phase Label(s): Na16.1Rh2.85Al21.8Si26.2Cl2.85O96[NH3]14.25[H2O]55.8
  • Structure Class(es): zeolite FAU
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cF1728
  • Space Group: 227
  • Phase Prototype: Na16.1Rh2.85(Al0.45Si0.55)48Cl2.85O96[NH3]14.25[H2O]55.8
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; STOE STADI P (determination of structural parameters), X-rays, Cu Kα1 (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): silicate, chloride, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, Rietveld refinement, RP = 0.0306; wRP = 0.0469
  • Sample Detail(s): sample prepared from Na-X zeolite, Rh[NH3]5ClCl2, energy-dispersive X-ray analysis; Rh content analyzed; degree of ion exchange α= 0.26, powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Na16.1Rh2.85Al21.8Si26.2Cl2.85O96[NH3]14.25[H2O]55.8
  • Alphabetic Formula: Al21.8Cl2.85[H2O]55.8[NH3]14.25Na16.1O96Rh2.85Si26.2
  • Published Formula: [Rh(NH3)5Cl]-exchanged zeolite NaX, Si/Al= 1.2, 26 % exchange
  • Refined Formula: Al21.84H111.55Na16.26O151.78Rh1.97Si26.16
  • Wyckoff Sequence: 227,i5hg6e3
  • Z Formula Units: 4
  • Density: ρ = 2.09 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1613414

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied