Inorganic Solid Phases

(Mn,Mg)3Zn2(OH)6[(As0.5H0.5)(O,OH)3]2 (HZn2Mn3AsO3[OH]9) Crystal Structure

General Information

  • Phase Label(s): HZn2Mn3AsO3[OH]9
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s): chlorophoenicite
  • Pearson Symbol: mS38
  • Space Group: 12
  • Phase Prototype: HZn2Mn3AsO3[OH]9
  • Measurement Detail(s): oscillation and rotation photographs (determination of cell parameters), diffractometer (determination of structural parameters), X-rays (determination of cell parameters), X-rays, Mo Kα (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, oxide
  • Interpretation Detail(s): positions of non-H atoms in average structure determined, full-matrix least-squares refinement; 330 reflections, R = 0.122
  • Sample Detail(s): chlorophoenicite sample from U.S.A. New Jersey, Sussex County, Franklin Furnace, chemical analysis; (Mn5.20Zn3.90Ca0.60Mg0.30)[OH]14[AsO4]2, single crystal (determination of cell parameters), single crystal, 0.019 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: HZn2Mn3AsO3[OH]9
  • Alphabetic Formula: AsHMn3O3[OH]9Zn2
  • Published Formula: (Mn,Mg)3Zn2(OH)6[(As0.5H0.5)(O,OH)3]2
  • Refined Formula: AsH10Mn3O12Zn2
  • Wyckoff Sequence: 12,i9a
  • Z Formula Units: 2
  • Density: ρ = 3.54 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1615494

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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