Inorganic Solid Phases

Na2.29Mn10[(Si11,V1)O34](OH)4 (Na2.29VMn10Si11O34[OH]4) Crystal Structure

General Information

  • Phase Label(s): Na2.29VMn10Si11O34[OH]4
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: aP63
  • Space Group: 2
  • Phase Prototype: Na2.29(V0.5Si0.5)2Mn10Si10O34[OH]4
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Philips PW1100 (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, silicate
  • Interpretation Detail(s): complete structure determined, least-squares refinement, R = 0.034
  • Sample Detail(s): sample from Italy, Apennines, Liguria, chemical analysis; 39.33 wt.% SiO2, 37.24 wt.% MnO, 6.44 wt.% Mn2O3, 0.32 wt.% FeO, 0.25 wt.% CaO, 6.60 wt.% V2O5, 0.29 wt.% As2O5, 4.53 wt.% Na2O, 5.00 wt.% H2O, single crystal (determination of cell parameters), single crystal, 0.02×0.04×0.05 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Na2.29VMn10Si11O34[OH]4
  • Alphabetic Formula: Mn10Na2.29O34[OH]4Si11V
  • Published Formula: Na2.29Mn10[(Si11,V1)O34](OH)4
  • Refined Formula: H4Mn10Na2.29O38Si11V
  • Wyckoff Sequence: 2,i31c
  • Z Formula Units: 1
  • Density: ρ = 3.51 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
β11 [nm2]
β22 [nm2]
β33 [nm2]
β12 [nm2]
β13 [nm2]
β23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1623961

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied