Inorganic Solid Phases

(Ba0.69Pb0.31)[(UO2)2V2O8]·5H2O (Ba0.69[UO2]2V2Pb0.31O8[H2O]5) Crystal Structure

General Information

  • Phase Label(s): Ba0.69[UO2]2V2Pb0.31O8[H2O]5
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s): francevillite
  • Pearson Symbol: oP88
  • Space Group: 60
  • Phase Prototype: (Ba0.96Pb0.04)[UO2]2V2O8[H2O]5
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Philips PW1100 (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 877 reflections; F > 6σ(F), R = 0.027; wR = 0.031
  • Sample Detail(s): francevillite sample from Gaboon, Mounana, single crystal (determination of cell parameters), single crystal, 0.013×0.050×0.16 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Ba0.69[UO2]2V2Pb0.31O8[H2O]5
  • Alphabetic Formula: Ba0.69[H2O]5O8Pb0.31[UO2]2V2
  • Published Formula: (Ba0.69Pb0.31)[(UO2)2V2O8]·5H2O
  • Refined Formula: Ba0.69H10O17Pb0.31U2V2
  • Wyckoff Sequence: 60,d10c2
  • Z Formula Units: 4
  • Density: ρ = 4.59 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
B11 [nm2]
B22 [nm2]
B33 [nm2]
B12 [nm2]
B13 [nm2]
B23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1624007

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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