Inorganic Solid Phases

[La(H2O)7Al(OH)6Mo6O18]·4nH2O (LaMo6AlO18[OH]6[H2O]11) Crystal Structure

General Information

  • Phase Label(s): LaMo6AlO18[OH]6[H2O]11
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: oP172
  • Space Group: 29
  • Phase Prototype: SmMo6AlO18[OH]6[H2O]11
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS SMART (determination of structural parameters), X-rays, Cu Kα; λ = 0.15418 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 5069 reflections; I > 2σ(I), R = 0.0329
  • Sample Detail(s): sample prepared from La[NO3]3[H2O]6, CH3COOH, Na2MoO4[H2O]2, AlCl3[H2O]6, HNO3, energy-dispersive X-ray analysis, thermogravimetry; Mo/La ratio 6/1, single crystal (determination of cell parameters), single crystal, 0.2×0.2×0.2 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: LaMo6AlO18[OH]6[H2O]11
  • Alphabetic Formula: Al[H2O]11LaMo6O18[OH]6
  • Published Formula: [La(H2O)7Al(OH)6Mo6O18]·4nH2O
  • Refined Formula: AlH28LaMo6O35
  • Wyckoff Sequence: 29,a43
  • Z Formula Units: 4
  • Density: ρ = 2.99 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1624234

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied