Inorganic Solid Phases

Na19K4[(SiW9O34)(SiW9O33(OH))(Cu(OH))6Cu]2X·nH2O, X= Cl, n= 90 (K4Na19Cu14W36[SiO4]4ClO118[OH]14[H2O]90) Crystal Structure

General Information

  • Phase Label(s): K4Na19Cu14W36[SiO4]4ClO118[OH]14[H2O]90
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mS2528
  • Space Group: 15
  • Phase Prototype: *
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, orthosilicate, chloride, oxide, hydrate
  • Interpretation Detail(s): cell parameters determined
  • Sample Detail(s): sample prepared from H5K6([SiW9O37]Cu3N3)[H2O]19, NaCl, chemical analysis; 53.98 wt.% W, 7.32 wt.% Cu, 4.08 wt.% Na, 1.26 wt.% K, 0.55 wt.% Cl, single crystal (determination of cell parameters)

Substance Summary

  • Standard Formula: K4Na19Cu14W36[SiO4]4ClO118[OH]14[H2O]90
  • Alphabetic Formula: ClCu14[H2O]90K4Na19O118[OH]14[SiO4]4W36
  • Published Formula: Na19K4[(SiW9O34)(SiW9O33(OH))(Cu(OH))6Cu]2X·nH2O, X= Cl, n= 90
  • Refined Formula:
  • Wyckoff Sequence:
  • Z Formula Units: 8
  • Density: ρ = 4.53 Mg·m−3

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Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Experimental Details

Reference

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1626036

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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