Inorganic Solid Phases

Bi12.8Co0.2Mo5O34+d (Mo5Co0.2Bi12.8O34.5) Crystal Structure

General Information

  • Phase Label(s): Mo5Co0.2Bi12.8O34.5
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP114
  • Space Group: 13
  • Phase Prototype: Mo5PbBi12O34
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Russia, Ekaterinburg, Zarechny, Institute of Nuclear Materials, IVV-2M reactor (determination of structural parameters), neutrons; λ = 0.15277 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide
  • Interpretation Detail(s): complete structure determined; composition dependence studied, Rietveld refinement, RP = 0.0328; wRP = 0.0432; RB = 0.06158
  • Sample Detail(s): sample prepared from Bi2O3, MoO3, Co3O4, energy-dispersive X-ray analysis; amounts of H(γ')-Bi2MoO6 (~ 0.1 wt.%), powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Mo5Co0.2Bi12.8O34.5
  • Alphabetic Formula: Bi12.8Co0.2Mo5O34.5
  • Published Formula: Bi12.8Co0.2Mo5O34+d
  • Refined Formula: Bi12.58Co0.24Mo4.79O32.01
  • Wyckoff Sequence: 13,g27f2e
  • Z Formula Units: 2
  • Density: ρ = 7.53 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1639367

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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