Inorganic Solid Phases

Na30.5K1.5[{Co4(OH)3PO4}4(A-α-GeW9O34)4]·116H2O (K0.75Na15.25W18Co8[GeO4]2[PO4]2O60[OH]6[H2O]58, T = 100(2) K) Crystal Structure

General Information

  • Phase Label(s): K0.75Na15.25W18Co8[GeO4]2[PO4]2O60[OH]6[H2O]58
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cF2560
  • Space Group: 203
  • Phase Prototype: K0.75Na15.25W18Co8[GeO4]2[PO4]2O60[OH]6[H2O]58
  • Measurement Detail(s): automatic diffractometer; 9940 (determination of cell parameters), automatic diffractometer; Bruker AXS D8 SMART APEX II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 100(2) K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): orthogermanate, hydroxide, orthophosphate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 139 variables; 3890 reflections; I > 2σ(I), R = 0.0733; wR = 0.1881
  • Sample Detail(s): sample prepared from CoCl2[H2O]6, Na10[A-α-GeW9O34][H2O]18, KOH, Na3PO4, HCl, chemical analysis, single crystal (determination of cell parameters), single crystal, 0.20×0.26×0.34 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: K0.75Na15.25W18Co8[GeO4]2[PO4]2O60[OH]6[H2O]58
  • Alphabetic Formula: Co8[GeO4]2[H2O]58K0.75Na15.25O60[OH]6[PO4]2W18
  • Published Formula: Na30.5K1.5[{Co4(OH)3PO4}4(A-α-GeW9O34)4]·116H2O
  • Refined Formula: Co8Ge2H39Na9O101.50P2W18
  • Wyckoff Sequence: 203,g25e5
  • Z Formula Units: 16
  • Density: ρ = 3.98 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1641253

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied