Inorganic Solid Phases

Bi4V1.2Sb0.8O11 (V0.75Bi2Sb0.25O5.35) Crystal Structure

General Information

  • Phase Label(s): V0.75Bi2Sb0.25O5.35
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: oF96
  • Space Group: 69
  • Phase Prototype: (V0.75Sb0.25)Bi2O5.35
  • Measurement Detail(s): automatic diffractometer; 25 (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of cell and structural parameters), T = 293 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide
  • Interpretation Detail(s): complete structure determined; composition dependence studied, least-squares refinement; 18 variables; 217 reflections, R = 0.120; wR = 0.144
  • Sample Detail(s): sample prepared from Bi2O3, Sb2O3 or Sb2O5, VO2 or V2O5, single crystal (determination of cell parameters), single crystal, 0.028×0.113×0.138 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: V0.6Bi2Sb0.4O5.5
  • Alphabetic Formula: Bi2O5.5Sb0.4V0.6
  • Published Formula: Bi4V1.2Sb0.8O11
  • Refined Formula: Bi2O5.50Sb0.40V0.60
  • Wyckoff Sequence: 69,p2oif
  • Z Formula Units: 4
  • Density: ρ = 8.20 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1702061

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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