Inorganic Solid Phases

(NH4)[Ir(NH3)Cl5] ([NH4]IrCl5[NH3]) Crystal Structure

General Information

  • Phase Label(s): [NH4]IrCl5[NH3]
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: tP18
  • Space Group: 104
  • Phase Prototype: [NH4]IrCl5[NH3]
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Siemens D5000 (determination of structural parameters), X-rays, Cu Kα1; λ = 0.154051 nm (determination of cell and structural parameters), T = 293 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): chloride
  • Interpretation Detail(s): positions of non-H atoms determined, Rietveld refinement; 26 variables, RP = 0.181; wRP = 0.201; RB = 0.103
  • Sample Detail(s): sample prepared from [NH4]2Ir[NH3]Cl5, Cl2, chemical analysis; Cl32.82H48.77Ir6.58N11.83, powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: [NH4]IrCl5[NH3]
  • Alphabetic Formula: Cl5Ir[NH3][NH4]
  • Published Formula: (NH4)[Ir(NH3)Cl5]
  • Refined Formula: Cl5H7IrN2
  • Wyckoff Sequence: 104,cba3
  • Z Formula Units: 2
  • Density: ρ = 2.98 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1702708

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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