Inorganic Solid Phases

[PbS]82.4[Bi2S3]17.6 (mol.%) (Pb6Bi2S9 hey) Crystal Structure

General Information

  • Phase Label(s): Pb6Bi2S9 hey
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s): heyrovskyite
  • Pearson Symbol: oS68
  • Space Group: 63
  • Phase Prototype: (Ag0.65Bi0.35)2Pb(Pb0.8Bi0.2)3Bi2S9
  • Measurement Detail(s): Guinier film (determination of cell parameters), Weissenberg photographs (determination of structural parameters), X-rays, Cu Kα1 (determination of cell parameters), X-rays (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): sulfide
  • Interpretation Detail(s): complete structure determined, trial-and-error
  • Sample Detail(s): sample prepared from PbS, Bi2S3, powder (determination of cell parameters), single crystal (determination of structural parameters)

Substance Summary

  • Standard Formula: Pb5.49Bi2.34S9
  • Alphabetic Formula: Bi2.34Pb5.49S9
  • Published Formula: [PbS]82.4[Bi2S3]17.6 (mol.%)
  • Refined Formula: Bi2Pb6S9
  • Wyckoff Sequence: 63,f7c2a
  • Z Formula Units: 4
  • Density: ρ = 7.17 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1709585

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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