Inorganic Solid Phases

Na6H14Cl4[Ni4(H2O)2(α-NiW9O34)2]·28H2O (H7Na3W9Ni3Cl2O34[H2O]15) Crystal Structure

General Information

  • Phase Label(s): H7Na3W9Ni3Cl2O34[H2O]15
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP272
  • Space Group: 14
  • Phase Prototype: H7Na3W9Ni3Cl2O34[H2O]15
  • Measurement Detail(s): automatic diffractometer; 250 (determination of cell parameters), automatic diffractometer; Bruker AXS SMART APEX II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 293(2) K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): chloride, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement on F2; 613 variables; 5834 reflections; I > 2σ(I), R = 0.0512; wR = 0.1225
  • Sample Detail(s): sample prepared from Na12P2W15O56[H2O]18, NiSO4[H2O]6, chemical analysis; 2.63 wt.% Na, 2.68 wt.% Cl, 6.19 wt.% Ni, 59.54 wt.% W, single crystal (determination of cell parameters), single crystal, 0.09×0.11×0.13 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: H7Na3W9Ni3Cl2O34[H2O]15
  • Alphabetic Formula: Cl2H7[H2O]15Na3Ni3O34W9
  • Published Formula: Na6H14Cl4[Ni4(H2O)2(α-NiW9O34)2]·28H2O
  • Refined Formula: Cl2H30Na3Ni3O49W9
  • Wyckoff Sequence: 14,e68
  • Z Formula Units: 4
  • Density: ρ = 4.21 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1714606

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied