Inorganic Solid Phases

H5K2Na[Mn2(H2O)6(H2W9.52Mo2.48O42)]Cl2·20H2O (H7K2NaW9.52Mo2.48Mn2Cl2O42[H2O]26) Crystal Structure

General Information

  • Phase Label(s): H7K2NaW9.52Mo2.48Mn2Cl2O42[H2O]26
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mS348
  • Space Group: 15
  • Phase Prototype: H7K2NaW6(W0.59Mo0.41)6Mn2Cl2O42[H2O]26
  • Measurement Detail(s): automatic diffractometer; Siemens SMART (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of structural parameters), T = 293(2) K (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): chloride, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement on F2; 394 variables; I > 2σ(I), R = 0.0403; wR = 0.1008
  • Sample Detail(s): sample prepared from Na2WO4[H2O]2, [NH4]6Mo7O24[H2O]4, Na2SeO3, MnCl2[H2O]4, chemical analysis; 0.65 wt.% Na, 2.36 wt.% K, 3.25 wt.% Mn, 51.34 wt.% W, 6.89 wt.% Mo, 2.11 wt.% Cl, single crystal (determination of structural parameters)

Substance Summary

  • Standard Formula: H7K2NaW9.52Mo2.48Mn2Cl2O42[H2O]26
  • Alphabetic Formula: Cl2H7[H2O]26K2Mn2Mo2.48NaO42W9.52
  • Published Formula: H5K2Na[Mn2(H2O)6(H2W9.52Mo2.48O42)]Cl2·20H2O
  • Refined Formula: Cl2K2Mn2Mo2.48NaO68W9.52
  • Wyckoff Sequence: 15,f42e3
  • Z Formula Units: 4
  • Density: ρ = 3.81 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1714609

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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