Inorganic Solid Phases

ZnCs2[Os(CN)6] (Cs2ZnOs[CN]6) Crystal Structure

General Information

  • Phase Label(s): Cs2ZnOs[CN]6
  • Structure Class(es): Nasicon family, Prussian blue
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cF64
  • Space Group: 225
  • Phase Prototype: Cs2LiCo[CN]6
  • Measurement Detail(s): automatic diffractometer; Siemens D5000 (determination of structural parameters), X-rays, Cu Kα (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): cyanide
  • Interpretation Detail(s): complete structure determined, Rietveld refinement, multiphase; 15 variables, wRP = 0.0998; RB = 0.0493
  • Sample Detail(s): sample prepared from Zn3K2(Os[CN]6)2[H2O]x, Cs+, energy-dispersive X-ray analysis; Zn/Cs/Os ratio 1/2/1; amounts of rhombohedral phase, powder (determination of structural parameters)

Substance Summary

  • Standard Formula: Cs2ZnOs[CN]6
  • Alphabetic Formula: [CN]6Cs2OsZn
  • Published Formula: ZnCs2[Os(CN)6]
  • Refined Formula: C6Cs2N6OsZn
  • Wyckoff Sequence: 225,e2cba
  • Z Formula Units: 4
  • Density: ρ = 3.79 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1717082

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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