Inorganic Solid Phases

[Zn(NH3)4]S2O8 (Zn[S2O8][NH3]4) Crystal Structure

General Information

  • Phase Label(s): Zn[S2O8][NH3]4
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: oP60
  • Space Group: 33
  • Phase Prototype: Zn[S2O8][NH3]4
  • Measurement Detail(s): automatic diffractometer; STOE STADI P (determination of structural parameters), X-rays, Cu Kα1; λ = 0.15406 nm (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): hexaoxo-μ-peroxodisulfate
  • Interpretation Detail(s): complete structure determined, Rietveld refinement, RP = 0.0340; wRP = 0.0344
  • Sample Detail(s): sample prepared from Zn[NH3]4[OH]2, [NH4]2S2O8, chemical analysis; 19.69 wt.% Zn, 58.83 wt.% [S2O8]2−, 17.07 wt.% N, 19.60 wt.% S, 3.52 wt.% H, powder (determination of structural parameters)

Substance Summary

  • Standard Formula: Zn[S2O8][NH3]4
  • Alphabetic Formula: [NH3]4[S2O8]Zn
  • Published Formula: [Zn(NH3)4]S2O8
  • Refined Formula: H12N4O8S2Zn
  • Wyckoff Sequence: 33,a15
  • Z Formula Units: 4
  • Density: ρ = 1.99 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1717570

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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