Inorganic Solid Phases

[Pd(NH3)4]3[Rh(NO2)6]2 (Rh2Pd3[NO2]12[NH3]12, T = 150 K) Crystal Structure

General Information

  • Phase Label(s): Rh2Pd3[NO2]12[NH3]12
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cF*
  • Space Group: 219
  • Phase Prototype: *
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS X8 SMART APEX (determination of structural parameters), X-rays, Mo Kα (determination of cell and structural parameters), T = 150 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): nitrite
  • Interpretation Detail(s): part of atom coordinates determined, least-squares refinement
  • Sample Detail(s): sample prepared from (Pd[NH3]4)[NO3]2, Na3(Rh[NO2]6), atomic absorption spectroscopy; 24.9 wt.% Pd, 16.1 wt.% Rh, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Rh2Pd3[NO2]12[NH3]12
  • Alphabetic Formula: [NH3]12[NO2]12Pd3Rh2
  • Published Formula: [Pd(NH3)4]3[Rh(NO2)6]2
  • Refined Formula:
  • Wyckoff Sequence: 219,h2fcba
  • Z Formula Units: 8
  • Density: ρ = 2.55 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1719595

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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