Inorganic Solid Phases

Rb13K2Na2[(α-Ti3GeW9O37OH)3(TiO3(OH2)3)]·40H2O (Rb13K2Na2Ti10W27[GeO4]3O102[OH]3[H2O]43, T = 173(2) K) Crystal Structure

General Information

  • Phase Label(s): Rb13K2Na2Ti10W27[GeO4]3O102[OH]3[H2O]43
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hR573
  • Space Group: 160
  • Phase Prototype: Rb13K2Na2Ti10W27[GeO4]3O102[OH]3[H2O]43
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS D8 APEX II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 173(2) K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): orthogermanate, hydroxide, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement on F2; 194 variables; 4468 reflections; I > 2σ(I), R = 0.0375; wR = 0.1078
  • Sample Detail(s): sample prepared from Na10[A-α-GeW9O34][H2O]23, K8(Ti4O4[C2O4]8), CH3COORb/CH3COOH, CH3COOLi/CH3COOH, chemical analysis; 0.56 wt.% Na, 1.33 wt.% K, 13.71 wt.% Rb, 2.29 wt.% Ge, 4.74 wt.% Ti, 50.34 wt.% W, single crystal (determination of cell parameters), single crystal, 0.05×0.14×0.15 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Rb13K2Na2Ti10W27[GeO4]3O102[OH]3[H2O]43
  • Alphabetic Formula: [GeO4]3[H2O]43K2Na2O102[OH]3Rb13Ti10W27
  • Published Formula: Rb13K2Na2[(α-Ti3GeW9O37OH)3(TiO3(OH2)3)]·40H2O
  • Refined Formula: Ge3H36K3O135Rb10Ti10W27
  • Wyckoff Sequence: 160,c22b19a2
  • Z Formula Units: 3
  • Density: ρ = 3.90 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1720906

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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