Inorganic Solid Phases

Bi4(V0.85Co0.15)2O11−d (V0.9Co0.1Bi2O5.35 rt) Crystal Structure

General Information

  • Phase Label(s): V0.9Co0.1Bi2O5.35 rt
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: tI42
  • Space Group: 139
  • Phase Prototype: (V0.85Mn0.15)Bi2O5.35
  • Measurement Detail(s): automatic diffractometer; 24 (determination of cell parameters), automatic diffractometer; France, Grenoble, Centre d'Etudes Nucléaires CEN, SILOE reactor, DN4 (determination of structural parameters), neutrons; λ = 0.11811 nm (determination of cell and structural parameters), T = 293 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide
  • Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement; 31 variables; 137 reflections, R = 0.048; wR = 0.067
  • Sample Detail(s): sample prepared from Bi2O3, V2O5, CoO, energy-dispersive X-ray analysis; V/Co ratio confirmed, single crystal (determination of cell parameters), single crystal, 4 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: V0.85Co0.15Bi2O5.312
  • Alphabetic Formula: Bi2Co0.15O5.312V0.85
  • Published Formula: Bi4(V0.85Co0.15)2O11−d
  • Refined Formula: Bi2.04Co0.13O5.31V0.84
  • Wyckoff Sequence: 139,n2e2dca
  • Z Formula Units: 2
  • Density: ρ = 7.72 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1804904

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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