Inorganic Solid Phases

Rb15.6Co0.2[Co9(OH)3(H2O)6(HPO4)2(PW9O34)3]·30H2O (Rb15.6W27Co9.2P3[PO4]2O102[OH]3[H2O]36) Crystal Structure

General Information

  • Phase Label(s): Rb15.6W27Co9.2P3[PO4]2O102[OH]3[H2O]36
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hP388
  • Space Group: 176
  • Phase Prototype: H2Rb15.6W27Co9.2[PO4]5O90[OH]3[H2O]36
  • Measurement Detail(s): automatic diffractometer; 25 (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, orthophosphate, phosphate, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 166 variables; 1058 reflections; F > 3σ(F), R = 0.093; wR = 0.106
  • Sample Detail(s): sample prepared from HPO42−, Co2+, WO42−, multi-phase sample, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Rb15.6W27Co9.2P3[PO4]2O102[OH]3[H2O]36
  • Alphabetic Formula: Co9.2[H2O]36O102[OH]3P3[PO4]2Rb15.6W27
  • Published Formula: Rb15.6Co0.2[Co9(OH)3(H2O)6(HPO4)2(PW9O34)3]·30H2O
  • Refined Formula: Co9H41O131P5Rb15.62W27
  • Wyckoff Sequence: 176,i26h11f2a
  • Z Formula Units: 2
  • Density: ρ = 4.35 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1812075

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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