Inorganic Solid Phases

Na4[Ni(NH3)][Ag(S2O3)2]2·NH3 (Na4Ag2Ni[S2O3]4[NH3]5) Crystal Structure

General Information

  • Phase Label(s): Na4Ag2Ni[S2O3]4[NH3]5
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: tI66
  • Space Group: 87
  • Phase Prototype: Na4Ag2Ni[S2O3]4[NH3]5
  • Measurement Detail(s): Guinier-Hägg film (determination of cell parameters), Weissenberg photographs (determination of structural parameters), X-rays, Cu Kα1 (determination of cell parameters), X-rays, Cu Kα (determination of structural parameters), T = 294 K (determination of cell parameters)
  • Phase Class(es):
  • Compound Class(es): thiosulfate
  • Interpretation Detail(s): positions of non-H atoms determined, least-squares refinement; 513 reflections, R = 0.079
  • Sample Detail(s): sample prepared from AgNO3, nickel tatraammine sulfate dihydrate, Na2S2O3[H2O]5, chemical analysis; 28.9 wt.% S, 9.5 wt.% NH3, 6.7 wt.% Ni, powder (determination of cell parameters), single crystal (determination of structural parameters)

Substance Summary

  • Standard Formula: Na4Ag2Ni[S2O3]4[NH3]5
  • Alphabetic Formula: Ag2[NH3]5Na4Ni[S2O3]4
  • Published Formula: Na4[Ni(NH3)][Ag(S2O3)2]2·NH3
  • Refined Formula: Ag2H15N5Na4NiO12S8
  • Wyckoff Sequence: 87,ih5eda
  • Z Formula Units: 2
  • Density: ρ = 2.64 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
β11 [nm2]
β22 [nm2]
β33 [nm2]
2β12 [nm2]
2β13 [nm2]
2β23 [nm2]

Powder Pattern

published defraction line
sin2(θ) [10−5]
computed diffraction line for Cu Kα
d [nm]
intensity
I [1]
h [1]
k [1]
l [1]
Radiation
Remark

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1815045

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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