Inorganic Solid Phases

K3H2[GeW8Mo3VO40]·4H2O (H2K3VW8Mo3[GeO4]O36[H2O]4) Crystal Structure

General Information

  • Phase Label(s): H2K3VW8Mo3[GeO4]O36[H2O]4
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mS362
  • Space Group: 5
  • Phase Prototype: H2K3(V0.08W0.67Mo0.25)12[GeO4]O36[H2O]4
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 295 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): orthogermanate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 467 variables; 2868 reflections; I > 3σ(I), R = 0.063; wR = 0.067
  • Sample Detail(s): sample prepared from GeO2 (α-quartz), NaVO3, Na2MoO4, Na2WO4, KCl, single crystal (determination of cell parameters), single crystal, 0.2×0.2×0.25 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: H2K3VW8Mo3[GeO4]O36[H2O]4
  • Alphabetic Formula: [GeO4]H2[H2O]4K3Mo3O36VW8
  • Published Formula: K3H2[GeW8Mo3VO40]·4H2O
  • Refined Formula: GeK3Mo3O43.67VW8
  • Wyckoff Sequence: 5,c88b4a
  • Z Formula Units: 6
  • Density: ρ = 3.47 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1818308

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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