Inorganic Solid Phases

Na28[{Co4(OH)3PO4}4(PW9O34)4]·58H2O (Na14W18Co8[PO4]4O60[OH]6[H2O]29) Crystal Structure

General Information

  • Phase Label(s): Na14W18Co8[PO4]4O60[OH]6[H2O]29
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: oP1324
  • Space Group: 60
  • Phase Prototype: Na14W18Co8[PO4]4O60[OH]6[H2O]29
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Rigaku R-AXIS RAPID (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 296 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, orthophosphate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement on F2; 1398 variables; 12880 reflections; I > 2σ(I), R = 0.0783; wR = 0.1817
  • Sample Detail(s): sample prepared from [(Co4[OH]3[PO4])4(PW9O34)4]28−, single crystal (determination of cell parameters), single crystal, 0.06×0.08×0.28 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Na14W18Co8[PO4]4O60[OH]6[H2O]29
  • Alphabetic Formula: Co8[H2O]29Na14O60[OH]6[PO4]4W18
  • Published Formula: Na28[{Co4(OH)3PO4}4(PW9O34)4]·58H2O
  • Refined Formula: Co8H64Na11O111P4W18
  • Wyckoff Sequence: 60,d165c
  • Z Formula Units: 8
  • Density: ρ = 3.41 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1831058

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied