Inorganic Solid Phases

Co0.8Ni0.2CrxFe2−xO4, x= 0.60; (Co2+0.104Ni2+0.022Fe3+0.874)[Co2+0.625Co3+0.071Ni2+0.178Cr2+0.108Cr3+0.492Fe2+0.088Fe3+0.438]O3.938 (Cr0.5Fe1.5Co0.5Ni0.5O4) Crystal Structure

General Information

  • Phase Label(s): Cr0.5Fe1.5Co0.5Ni0.5O4
  • Structure Class(es): spinel family
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: cF56
  • Space Group: 227
  • Phase Prototype: MgAl2O4
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Philips X'Pert MPD (determination of structural parameters), X-rays, Cu Kα (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): oxide
  • Interpretation Detail(s): complete structure determined; composition dependence studied, Rietveld refinement
  • Sample Detail(s): sample prepared from Co[NO3]2[H2O]6, Ni[NO3]2[H2O]6, Fe[NO3]3[H2O]9, Cr[NO3]3[H2O]9, powder (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: Cr0.6Fe1.4Co0.8Ni0.2O3.938
  • Alphabetic Formula: Co0.8Cr0.6Fe1.4Ni0.2O3.938
  • Published Formula: Co0.8Ni0.2CrxFe2−xO4, x= 0.60; (Co2+0.104Ni2+0.022Fe3+0.874)[Co2+0.625Co3+0.071Ni2+0.178Cr2+0.108Cr3+0.492Fe2+0.088Fe3+0.438]O3.938
  • Refined Formula: Co0.80Cr0.60Fe1.40Ni0.20O3.94
  • Wyckoff Sequence: 227,ecb
  • Z Formula Units: 8
  • Density: ρ = 5.22 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1831580

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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