Inorganic Solid Phases

[(NH3)4Co(NH2)(NO2)Co(NH3)4]Cl4·4H2O (Co2[NH2][NO2]Cl4[NH3]8[H2O]4) Crystal Structure

General Information

  • Phase Label(s): Co2[NH2][NO2]Cl4[NH3]8[H2O]4
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP44
  • Space Group: 11
  • Phase Prototype: Co2[NH2][NO2]Cl4[NH3]8[H2O]4
  • Measurement Detail(s): Weissenberg photographs (determination of cell parameters), automatic diffractometer; General Electric (determination of structural parameters), X-rays (determination of cell parameters), X-rays, Cu Kα (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): amide, nitrite, chloride, hydrate
  • Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement; 115 variables; 1071 reflections, R = 0.048
  • Sample Detail(s): sample prepared from [NH2]O2Co[NH3]4[NO3]4, single crystal (determination of cell parameters), single crystal, 0.04×0.05×0.06 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Co2[NH2][NO2]Cl4[NH3]8[H2O]4
  • Alphabetic Formula: Cl4Co2[H2O]4[NH2][NH3]8[NO2]
  • Published Formula: [(NH3)4Co(NH2)(NO2)Co(NH3)4]Cl4·4H2O
  • Refined Formula: Cl4Co2H34N10O6
  • Wyckoff Sequence: 11,f6e10
  • Z Formula Units: 2
  • Density: ρ = 1.76 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
B [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
β11 [nm2]
β22 [nm2]
β33 [nm2]
β12 [nm2]
β13 [nm2]
β23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1905137

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied