Inorganic Solid Phases

[Pt(NH3)4][Pt(NH3)4I2[HSO4]3[OH]·H2O (H3Pt2[SO4]3I2[OH][NH3]8[H2O]) Crystal Structure

General Information

  • Phase Label(s): H3Pt2[SO4]3I2[OH][NH3]8[H2O]
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: oP144
  • Space Group: 62
  • Phase Prototype: H3Pt2[SO4]3I2[OH][NH3]8[H2O]
  • Measurement Detail(s): automatic diffractometer; Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, sulfate, iodide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 1652 reflections; I > 1.5σ(I), R = 0.0484; wR = 0.0513
  • Sample Detail(s): sample prepared from Magnus green, KI, H2SO4, chemical analysis; 2.60 wt.% H, 15.1 wt.% Br, 10.4 wt.% N, 11.5 wt.% S, single crystal, 0.088×0.113×0.206 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: H3Pt2[SO4]3I2[OH][NH3]8[H2O]
  • Alphabetic Formula: H3[H2O]I2[NH3]8[OH]Pt2[SO4]3
  • Published Formula: [Pt(NH3)4][Pt(NH3)4I2[HSO4]3[OH]·H2O
  • Refined Formula: H27I2N8O14Pt2S3
  • Wyckoff Sequence: 62,d13c10
  • Z Formula Units: 4
  • Density: ρ = 2.86 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1905921

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

    Citation copied