Inorganic Solid Phases

[H3O][Pt{S2C2(CN)2}2]·H2O ([H3O]PtC4S4[CN]4[H2O]) Crystal Structure

General Information

  • Phase Label(s): [H3O]PtC4S4[CN]4[H2O]
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: aP38
  • Space Group: 2
  • Phase Prototype: RbPtC4S4[CN]4[H2O]
  • Measurement Detail(s): automatic diffractometer; 25 (determination of cell parameters), automatic diffractometer; Enraf-Nonius CAD4 (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): cyanide, hydrate
  • Interpretation Detail(s): positions of non-H and part of H atoms determined, full-matrix least-squares refinement; 185 variables; 2220 reflections; I > 1.5σ(I), R = 0.041; wR = 0.051
  • Sample Detail(s): sample prepared from [N(C2H5)4]2(Pt[S2C2][CN]2), NH4Cl, chemical analysis; 18.45 wt.% C, 1.3 wt.% H, 13.45 wt.% N, single crystal (determination of cell and structural parameters)

Substance Summary

  • Standard Formula: [H3O]PtC4S4[CN]4[H2O]
  • Alphabetic Formula: C4[CN]4[H2O][H3O]PtS4
  • Published Formula: [H3O][Pt{S2C2(CN)2}2]·H2O
  • Refined Formula: C8H5N4O2PtS4
  • Wyckoff Sequence: 2,i19
  • Z Formula Units: 2
  • Density: ρ = 2.48 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1905968

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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