Inorganic Solid Phases

Pb2+4{Co2[B(OH)2P2O8](PO4)2}Cl (Co2Pb4BP2[PO4]2ClO8[OH]2) Crystal Structure

General Information

  • Phase Label(s): Co2Pb4BP2[PO4]2ClO8[OH]2
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: hR540
  • Space Group: 167
  • Phase Prototype: Co2Pb4BP2[PO4]2ClO8[OH]2
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS SMART APEX II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 293(2) K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, orthophosphate, borate, phosphate, chloride
  • Interpretation Detail(s): complete structure determined, full-matrix least-squares refinement on F2; 137 variables; I > 2σ(I), R = 0.0498; wR = 0.1318
  • Sample Detail(s): sample prepared from Co[Oac]2[H2O]4, PbB2O4[H2O], H3BO3, H3PO4, HCl, energy-dispersive X-ray analysis, inductive coupled plasma method; 58.36 wt.% Pb, 7.94 wt.% Co, 8.73 wt.% P, 0.79 wt.% B, single crystal (determination of cell parameters), single crystal, 0.13×0.23×0.26 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Co2Pb4BP2[PO4]2ClO8[OH]2
  • Alphabetic Formula: BClCo2O8[OH]2P2[PO4]2Pb4
  • Published Formula: Pb2+4{Co2[B(OH)2P2O8](PO4)2}Cl
  • Refined Formula: BClCo2H2O18P4Pb4
  • Wyckoff Sequence: 167,f13ec4b
  • Z Formula Units: 18
  • Density: ρ = 5.61 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1931114

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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