Inorganic Solid Phases

Na10H8[Mn6Ge3W24O94(H2O)2]·37H2O (H8Na10W24Mn6[GeO4]3O82[H2O]39) Crystal Structure

General Information

  • Phase Label(s): H8Na10W24Mn6[GeO4]3O82[H2O]39
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP764
  • Space Group: 14
  • Phase Prototype: H8Na10W24Mn6[GeO4]3O82[H2O]39
  • Measurement Detail(s): automatic diffractometer (determination of cell parameters), automatic diffractometer; Bruker AXS SMART APEX II (determination of structural parameters), X-rays, Mo Kα; λ = 0.071073 nm (determination of cell and structural parameters), T = 296(2) K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): orthogermanate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined, full-matrix least-squares refinement; 1485 variables; 13873 reflections; I > 2σ(I), R = 0.0562; wR = 0.1485
  • Sample Detail(s): sample prepared from Na2WO4, GeO2 (α-quartz), HCl, Mn(CH3COO)2[H2O]4, chemical analysis; 59.33 wt.% W, 4.57 wt.% Mn, 2.85 wt.% Ge, 3.19 wt.% Na, 28.81 wt.% O, 1.25 wt.% H, single crystal (determination of cell parameters), single crystal, 0.4×0.4×0.4 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: H8Na10W24Mn6[GeO4]3O82[H2O]39
  • Alphabetic Formula: [GeO4]3H8[H2O]39Mn6Na10O82W24
  • Published Formula: Na10H8[Mn6Ge3W24O94(H2O)2]·37H2O
  • Refined Formula: Ge3H78Mn6Na10O133W24
  • Wyckoff Sequence: 14,e191
  • Z Formula Units: 4
  • Density: ρ = 3.45 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1931352

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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