Inorganic Solid Phases

[Ag12(OH)2(H2O)4KNa(P2Mo5O23)2] (KNaAg12Mo10[PO4]4O30[OH]2[H2O]4, T = 184.5 K) Crystal Structure

General Information

  • Phase Label(s): KNaAg12Mo10[PO4]4O30[OH]2[H2O]4
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: mP162
  • Space Group: 7
  • Phase Prototype: KNaAg12Mo10[PO4]4O30[OH]2[H2O]4
  • Measurement Detail(s): automatic diffractometer; 25 (determination of cell parameters), automatic diffractometer; Bruker AXS SMART (determination of structural parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of cell and structural parameters), T = 184.5 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, orthophosphate, oxide, hydrate
  • Interpretation Detail(s): positions of non-H atoms determined; absolute structure determined, full-matrix least-squares refinement on F2; 731 variables; 6754 reflections; I > 2σ(I), R = 0.0402; wR = 0.1325
  • Sample Detail(s): sample prepared from Na2MoO4[H2O]2, NaH2PO4, AgNO3, HNO3, C2H5OH (ethanol), chemical analysis; 39.36 % Ag, 1.12 % K, 29.29 % Mo, 0.75 % Na, single crystal (determination of cell parameters), single crystal, 0.111×0.112×0.112 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: KNaAg12Mo10[PO4]4O30[OH]2[H2O]4
  • Alphabetic Formula: Ag12[H2O]4KMo10NaO30[OH]2[PO4]4
  • Published Formula: [Ag12(OH)2(H2O)4KNa(P2Mo5O23)2]
  • Refined Formula: Ag12H10KMo10NaO52P4
  • Wyckoff Sequence: 7,a81
  • Z Formula Units: 2
  • Density: ρ = 4.73 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Displacement Parameters

Isotropic

Site
Published
U [nm2]
Type
Computed
Beq [nm2]

Anisotropic

Site
U11 [nm2]
U22 [nm2]
U33 [nm2]
U12 [nm2]
U13 [nm2]
U23 [nm2]

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_1937377

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

  • Cite this content

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