Inorganic Solid Phases

Na5HMo5P2O23(H2O)11 (Na5Mo5P2O22[OH][H2O]11) Crystal Structure

General Information

  • Phase Label(s): Na5Mo5P2O22[OH][H2O]11
  • Structure Class(es):
  • Classification by Properties:
  • Mineral Name(s):
  • Pearson Symbol: aP101
  • Space Group: 2
  • Phase Prototype: Na5Mo5P2O22[OH][H2O]11
  • Measurement Detail(s): Guinier-Hägg film (determination of cell parameters), automatic diffractometer; Philips PAILRED (determination of structural parameters), X-rays, Cu Kα1; λ = 0.154051 nm (determination of cell parameters), X-rays, Mo Kα; λ = 0.071069 nm (determination of structural parameters), T = 298 K (determination of cell and structural parameters)
  • Phase Class(es):
  • Compound Class(es): hydroxide, phosphate, hydrate
  • Interpretation Detail(s): average structure determined, least-squares refinement; 3246 reflections; I > 2σ(I), R = 0.036; wR = 0.051
  • Sample Detail(s): sample prepared from Na2MoO4[H2O], Na2HPO4[H2O], HClO3, chemical analysis; H33.52Mo7.34Na7.26O49.00P2.88, powder (determination of cell parameters), single crystal, 0.20×0.18×0.35 mm3 (determination of structural parameters)

Substance Summary

  • Standard Formula: Na5Mo5P2O22[OH][H2O]11
  • Alphabetic Formula: [H2O]11Mo5Na5O22[OH]P2
  • Published Formula: Na5HMo5P2O23(H2O)11
  • Refined Formula: H23Mo5Na5O34P2
  • Wyckoff Sequence: 2,i50b
  • Z Formula Units: 2
  • Density: ρ = 2.73 Mg·m−3

Crystallographic Data

Cell Parameters

Published Data
Standardized Data
Unit Cell
Niggli-Reduced Cell
Space Group
a
b
c
α
β
γ
a/b
b/c
c/a
V

Atom Coordinates

Standardized

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation
Co-ord. No.
Atomic Env.

Published

Site
Element
Wyckoff Symbol
Symmetry
X
Y
Z
Occupation

Experimental Details

Reference

3D Interactive Structure

About this content

  • Database name

    PAULING FILE Multinaries Edition – 2012

  • Dataset ID

    sd_2041962

  • Copyright

    ©Springer & Material Phases Data System (MPDS), Switzerland & National Institute for Materials Science (NIMS), Japan, 2016

  • Chief Editor

    Pierre Villars, Material Phases Data System (MPDS), CH-6354 Vitznau, Switzerland

    villars.mpds@bluewin.ch

  • Credits

    SpringerMaterials Release 2016.

    Data generated pre-2002: © Springer & MPDS & NIMS; post-2001: © Springer & MPDS

    All Rights Reserved. Version 2016.10.

    Project Coordinator: Shuichi Iwata

    Section-Editor: Karin Cenzual (Crystal Structures)

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